Available PAW potentials: Difference between revisions

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PAW potentials for all elements in the periodic table are available. With the exception of the 1st row elements, all PAW potentials were generated to work reliably and accurately at an energy cutoff of roughly 250 eV (the default energy cutoff is read as {{TAG|ENMAX}} in the [[POTCAR]] file).
#REDIRECT [[Available pseudopotentials]]
The distributed PAW potentials have been generated by G. Kresse following the recipes discussed in {{cite|kresse:prb:99}}, whereas the PAW method has been first suggested and used by Peter Blöchl {{cite|bloechl:prb:94b}}.
If you use any of the supplied PAW potentials you should include these two references.
 
Generally the PAW potentials are more accurate than ultra-soft pseudopotentials (US-PP). There are two reasons for this: first, the radial cutoffs (core radii) are smaller than the radii used for US pseudopotentials, and second the PAW potentials reconstruct the exact valence wavefunction with all nodes in the core region. Since the core radii of the PAW potentials are smaller, the required energy cutoffs and basis sets are also somewhat larger. If such a high precision is not required, the older US-PP can be used. In practice, however, the increase in the basis set size will be usually small, since the energy cutoffs have not changed appreciably for C, N and O, so that calculations for model structures that include any of these elements are not more expensive with PAW than with US-PP.
 
For some elements several PAW versions exist. The standard version has generally no extension. An extension _h implies that the potential is harder than the standard potential and hence requires a greater energy cutoff. The extension _s means that the potential is softer than the standard version. The extensions _pv and _sv imply that the <math>p</math> and <math>s</math> semi-core states are treated as valence states (i.e. for V_pv the <math>3p</math> states are treated as valence states, and for V_sv the <math>3s</math> and <math>3p</math> states are treated as valence states). PAW files with an extension _d, treat the <math>d</math> semi core states as valence states (for Ga_d the <math>3d</math> states are treated as valence states).
 
In the following we will present the available PAW potentials. All distributed potentials have been tested using standard DFT-"benchmark" runs (see the ''data_base'' file in the released tar files). We strongly recommend to use the potentials only in VASP.5.4 or higher.
 
Recommended potentials are always reported in bold face.
 
The corresponding distribution directory of the potential is created by adding underscores between the elemental name and the extensions ``_'', e.g Li sv becomes Li_sv. All reported potentials are for PBE calculations. The reported cutoffs might differ slightly for LDA potentials.
 
== Recommended potentials for DFT calculations ==
 
The following table lists the standard PAW potentials for VASP.
 
'''Important Note''': If dimers with short bonds are present in the compound (O<sub>2</sub>, CO, N<sub>2</sub>, F<sub>2</sub>, P<sub>2</sub>, S<sub>2</sub>, Cl<sub>2</sub>), we recommend to use the _h potentials. Specifically, C_h, O_h, N_h, F_h, P_h, S_h, Cl_h.
 
{| class="wikitable"
|-
|Element (and appendix) ||default cutoff ENMAX (eV) ||valency
|-
|'''H''' ||'''250''' ||'''1'''
|-             
|H AE ||1000 ||1
|-             
|H h ||700 ||1
|-             
|H s ||200 ||1
|-             
|'''He''' ||'''479''' ||'''2'''
|-             
|Li ||140 ||1
|-             
|'''Li sv''' ||'''499''' ||'''3'''
|-             
|'''Be''' ||'''248''' ||'''2'''
|-             
|Be sv ||309 ||4
|-             
|'''B''' ||'''319''' ||'''3'''
|-             
|B h ||700 ||3
|-             
|B s ||269 ||3
|-             
|'''C''' ||'''400''' ||'''4'''
|-             
|C h ||700 ||4
|-             
|C s ||274 ||4
|-             
|'''N''' ||'''400''' ||'''5'''
|-             
|N h ||700 ||5
|-             
|N s ||280 ||5
|-             
|'''O''' ||'''400''' ||'''6'''
|-             
|O h ||700 ||6
|-             
|O s ||283 ||6
|-             
|'''F''' ||'''400''' ||'''7'''
|-             
|F h ||700 ||7
|-             
|F s ||290 ||7
|-             
|'''Ne''' ||'''344''' ||'''8'''
|-             
|Na ||102 ||1
|-             
|'''Na pv''' ||'''260''' ||'''7'''
|-             
|Na sv ||646 ||9
|-             
|'''Mg''' ||'''200''' ||'''2'''
|-             
|Mg pv ||404 ||8
|-             
|Mg sv ||495 ||10
|-             
|'''Al''' ||'''240''' ||'''3'''
|-             
|'''Si''' ||'''245''' ||'''4'''
|-             
|'''P''' ||'''255''' ||'''5'''
|-             
|P h ||390 ||5
|-             
|'''S''' ||'''259''' ||'''6'''
|-             
|S h ||402 ||6
|-             
|'''Cl''' ||'''262''' ||'''7'''
|-             
|Cl h ||409 ||7
|-             
|'''Ar''' ||'''266''' ||'''8'''
|-             
|K pv ||117 ||7
|-             
|'''K sv''' ||'''259''' ||'''9'''
|-             
|Ca pv ||120 ||8
|-             
|'''Ca sv''' ||'''267''' ||'''10'''
|-             
|Sc ||155 ||3
|-             
|'''Sc sv''' ||'''223''' ||'''11'''
|-             
|Ti ||178 ||4
|-             
|Ti pv ||222 ||10
|-             
|'''Ti sv''' ||'''275''' ||'''12'''
|-             
|V ||193 ||5
|-             
|V pv ||264 ||11
|-             
|'''V sv''' ||'''264''' ||'''13'''
|-             
|Cr ||227 ||6
|-             
|'''Cr pv''' ||'''266''' ||'''12'''
|-             
|Cr sv ||395 ||14
|-             
|Mn ||270 ||7
|-             
|'''Mn pv''' ||'''270''' ||'''13'''
|-             
|Mn sv ||387 ||15
|-             
|'''Fe''' ||'''268''' ||'''8'''
|-             
|Fe pv ||293 ||14
|-             
|Fe sv ||391 ||16
|-             
|'''Co''' ||'''268''' ||'''9'''
|-             
|Co pv ||271 ||15
|-             
|Co sv ||390 ||17
|-             
|'''Ni''' ||'''270''' ||'''10'''
|-             
|Ni pv ||368 ||16
|-             
|'''Cu''' ||'''295''' ||'''11'''
|-             
|Cu pv ||369 ||17
|-             
|'''Zn''' ||'''277''' ||'''12'''
|-             
|Ga ||135 ||3
|-             
|'''Ga d''' ||'''283''' ||'''13'''
|-             
|Ga h ||405 ||13
|-             
|Ge ||174 ||4
|-             
|'''Ge d''' ||'''310''' ||'''14'''
|-             
|Ge h ||410 ||14
|-             
|'''As''' ||'''209''' ||'''5'''
|-             
|As d ||289 ||15
|-             
|'''Se''' ||'''212''' ||'''6'''
|-             
|'''Br''' ||'''216''' ||'''7'''
|-             
|'''Kr''' ||'''185''' ||'''8'''
|-             
|Rb pv ||122 ||7
|-             
|'''Rb sv''' ||'''220''' ||'''9'''
|-             
|'''Sr sv''' ||'''229''' ||'''10'''
|-             
|'''Y sv''' ||'''203''' ||'''11'''
|-             
|'''Zr sv''' ||'''230''' ||'''12'''
|-             
|Nb pv ||209 ||11
|-             
|'''Nb sv''' ||'''293''' ||'''13'''
|-             
|Mo ||225 ||6
|-             
|Mo pv ||225 ||12
|-             
|'''Mo sv''' ||'''243''' ||'''14'''
|-             
|Tc ||229 ||7
|-             
|'''Tc pv''' ||'''264''' ||'''13'''
|-             
|Tc sv ||319 ||15
|-             
|Ru ||213 ||8
|-             
|'''Ru pv''' ||'''240''' ||'''14'''
|-             
|Ru sv ||319 ||16
|-             
|Rh ||229 ||9
|-             
|'''Rh pv''' ||'''247''' ||'''15'''
|-             
|'''Pd''' ||'''251''' ||'''10'''
|-             
|Pd pv ||251 ||16
|-             
|'''Ag''' ||'''250''' ||'''11'''
|-             
|Ag pv ||298 ||17
|-             
|'''Cd''' ||'''274''' ||'''12'''
|-             
|In ||96 ||3
|-             
|'''In d''' ||'''239''' ||'''13'''
|-             
|Sn ||103 ||4
|-             
|'''Sn d''' ||'''241''' ||'''14'''
|-             
|'''Sb''' ||'''172''' ||'''5'''
|-             
|'''Te''' ||'''175''' ||'''6'''
|-             
|'''I''' ||'''176''' ||'''7'''
|-             
|'''Xe''' ||'''153''' ||'''8'''
|-             
|'''Cs sv''' ||'''220''' ||'''9'''
|-             
|'''Ba sv''' ||'''187''' ||'''10'''
|-             
|'''La''' ||'''219''' ||'''11'''
|-             
|La s ||137 ||9
|-             
|'''Ce''' ||'''273''' ||'''12'''
|-             
|Ce h ||300 ||12
|-             
|Ce 3 ||177 ||11
|-             
|Pr ||273 ||13
|-             
|'''Pr 3''' ||'''182''' ||'''11'''
|-             
|Nd ||253 ||14
|-             
|'''Nd 3''' ||'''183''' ||'''11'''
|-             
|Pm ||259 ||15
|-             
|'''Pm 3''' ||'''177''' ||'''11'''
|-             
|Sm ||258 ||16
|-             
|'''Sm 3''' ||'''177''' ||'''11'''
|-             
|Eu ||250 ||17
|-             
|'''Eu 2''' ||'''99''' ||'''8'''
|-             
|Eu 3 ||129 ||9
|-             
|Gd ||256 ||18
|-             
|'''Gd 3''' ||'''154''' ||'''9'''
|-             
|Tb ||265 ||19
|-             
|'''Tb 3''' ||'''156''' ||'''9'''
|-             
|Dy ||255 ||20
|-             
|'''Dy 3''' ||'''156''' ||'''9'''
|-             
|Ho ||257 ||21
|-             
|'''Ho 3''' ||'''154''' ||'''9'''
|-             
|Er 2 ||120 ||8
|-             
|'''Er 3''' ||'''155''' ||'''9'''
|-             
|Er ||298 ||22
|-             
|Tm ||257 ||23
|-             
|'''Tm 3''' ||'''149''' ||'''9'''
|-             
|Yb ||253 ||24
|-             
|'''Yb 2''' ||'''113''' ||'''8'''
|-             
|Lu ||256 ||25
|-             
|'''Lu 3''' ||'''155''' ||'''9'''
|-             
|Hf ||220 ||4
|-             
|'''Hf pv''' ||'''220''' ||'''10'''
|-             
|Hf sv ||237 ||12
|-             
|Ta ||224 ||5
|-             
|'''Ta pv''' ||'''224''' ||'''11'''
|-             
|W ||223 ||6
|-             
|'''W pv''' ||'''223''' ||'''12'''
|-             
|'''Re''' ||'''226''' ||'''7'''
|-             
|Re pv ||226 ||13
|-             
|'''Os''' ||'''228''' ||'''8'''
|-             
|Os pv ||228 ||14
|-             
|'''Ir''' ||'''211''' ||'''9'''
|-             
|'''Pt''' ||'''230''' ||'''10'''
|-             
|Pt pv ||295 ||16
|-             
|'''Au''' ||'''230''' ||'''11'''
|-             
|'''Hg''' ||'''233''' ||'''12'''
|-             
|Tl ||90 ||3
|-             
|'''Tl d''' ||'''237''' ||'''13'''
|-             
|Pb ||98 ||4
|-             
|'''Pb d''' ||'''238''' ||'''14'''
|-             
|Bi ||105 ||5
|-             
|'''Bi d''' ||'''243''' ||'''15'''
|-             
|Po ||160 ||6
|-             
|'''Po d''' ||'''265''' ||'''16'''
|-             
|At ||161 ||7
|-             
|'''At d''' ||'''266''' ||'''17'''
|-             
|'''Rn''' ||'''152''' ||'''8'''
|-             
|'''Fr sv''' ||'''215''' ||'''9'''
|-             
|'''Ra sv''' ||'''237''' ||'''10'''
|-             
|'''Ac''' ||'''172''' ||'''11'''
|-             
|'''Th''' ||'''247''' ||'''12'''
|-             
|Th s ||169 ||10
|-             
|'''Pa''' ||'''252''' ||'''13'''
|-             
|Pa s ||193 ||11
|-             
|'''U''' ||'''253''' ||'''14'''
|-             
|U s ||209 ||14
|-             
|'''Np''' ||'''254''' ||'''15'''
|-             
|Np s ||208 ||15
|-             
|'''Pu''' ||'''254''' ||'''16'''
|-             
|Pu s ||208 ||16
|-             
|'''Am''' ||'''256''' ||'''17'''
|-             
|'''Cm''' ||'''258''' ||'''18'''
|-
|}
 
Hydrogen like potentials are supplied for a valency between 0.25 and 1.75 as listed in the table below:
 
{| class="wikitable"
|-
|Element (and appendix)        ||default cutoff ENMAX (eV)    ||valency
|-
|H .25          ||250  ||0.2500
|-
|H .33          ||250  ||0.3300
|-
|H .42          ||250  ||0.4200
|-
|H .5          ||250  ||0.5000
|-
|H .58          ||250  ||0.5800
|-
|H .66          ||250  ||0.6600
|-
|H .75          ||250  ||0.7500
|-
|H 1.25        ||250  ||1.2500
|-
|H 1.33        ||250  ||1.3300
|-
|H 1.5          ||250  ||1.5000
|-
|H 1.66        ||250  ||1.6600
|-
|H 1.75        ||250  ||1.7500
|-
|}
 
== Recommended potentials for GW/RPA calculations ==
 
The available GW potentials are listed in the Table below. As documented in the ''data_base'' file released with the PAW potentials, for density functional calculations, the GW potentials yield virtually identical results as the standard potentials, and it is safe to assume that one can use the GW potentials instead of standard LDA/GGA potentials for groundstate calculations without deteriorating the results. In fact, we believe the GW potentials are generally at least as good as the DFT standard potentials, but might be much better for excited state properties.
 
In general, the GW potentials yield much better scattering properties at high energies well above the Fermi-level (typically up to 10-20 Ry above the vacuum level). This is believed to be important for GW and RPA calculations.
 
'''Important Note''': If dimers with short bonds are present in the compound (O<sub>2</sub>, CO, N<sub>2</sub>, F<sub>2</sub>, P<sub>2</sub>, S<sub>2</sub>, Cl<sub>2</sub>), we recommend to use the _h potentials. Specifically, C_GW_h, O_GW_h, N_GW_h, F_GW_h.
 
{| class="wikitable"
|-
|Element (and appendix) ||default cutoff ENMAX (eV) ||valency
|-
|'''H GW''' ||'''300''' ||'''1'''
|-
|H h GW ||700 ||1
|-
|'''He GW''' ||'''405''' ||'''2'''
|-
|'''Li sv GW''' ||'''434''' ||'''3'''
|-
|Li GW ||112 ||1
|-
|Li AE GW ||434 ||3
|-
|'''Be sv GW''' ||'''537''' ||'''4'''
|-
|Be GW ||248 ||2
|-
|'''B GW''' ||'''319''' ||'''3'''
|-
|'''C GW''' ||'''414''' ||'''4'''
|-
|C GW new ||414 ||4
|-
|C h GW ||741 ||4
|-
|'''N GW''' ||'''421''' ||'''5'''
|-
|N GW new ||421 ||5
|-
|N h GW ||755 ||5
|-
|N s GW ||296 ||5
|-
|'''O GW''' ||'''415''' ||'''6'''
|-
|O GW new ||434 ||6
|-
|O h GW ||765 ||6
|-
|O s GW ||335 ||6
|-
|'''F GW''' ||'''488''' ||'''7'''
|-
|F GW new ||488 ||7
|-
|F h GW ||848 ||7
|-
|'''Ne GW''' ||'''432''' ||'''8'''
|-
|Ne s GW ||318 ||8
|-
|'''Na sv GW''' ||'''372''' ||'''9'''
|-
|'''Mg sv GW''' ||'''430''' ||'''10'''
|-
|Mg GW ||126 ||2
|-
|Mg pv GW ||404 ||8
|-
|'''Al GW''' ||'''240''' ||'''3'''
|-
|Al sv GW ||411 ||11
|-
|'''Si GW''' ||'''245''' ||'''4'''
|-
|Si GW new ||245 ||4
|-
|Si sv GW ||548 ||12
|-
|'''P GW''' ||'''255''' ||'''5'''
|-
|'''S GW''' ||'''259''' ||'''6'''
|-
|'''Cl GW''' ||'''262''' ||'''7'''
|-
|'''Ar GW''' ||'''290''' ||'''8'''
|-
|'''K sv GW''' ||'''249''' ||'''9'''
|-
|'''Ca sv GW''' ||'''281''' ||'''10'''
|-
|'''Sc sv GW''' ||'''378''' ||'''11'''
|-
|'''Ti sv GW''' ||'''383''' ||'''12'''
|-
|'''V sv GW''' ||'''382''' ||'''13'''
|-
|'''Cr sv GW''' ||'''384''' ||'''14'''
|-
|'''Mn sv GW''' ||'''384''' ||'''15'''
|-
|Mn GW ||278 ||7
|-
|'''Fe sv GW''' ||'''387''' ||'''16'''
|-
|Fe GW ||321 ||8
|-
|'''Co sv GW''' ||'''387''' ||'''17'''
|-
|Co GW ||323 ||9
|-
|'''Ni sv GW''' ||'''389''' ||'''18'''
|-
|Ni GW ||357 ||10
|-
|'''Cu sv GW''' ||'''467''' ||'''19'''
|-
|Cu GW ||417 ||11
|-
|'''Zn sv GW''' ||'''401''' ||'''20'''
|-
|Zn GW ||328 ||12
|-
|'''Ga d GW''' ||'''404''' ||'''13'''
|-
|Ga GW ||135 ||3
|-
|Ga sv GW ||404 ||21
|-
|'''Ge d GW''' ||'''375''' ||'''14'''
|-
|Ge sv GW ||410 ||22
|-
|Ge GW ||174 ||4
|-
|'''As GW''' ||'''209''' ||'''5'''
|-
|As sv GW ||415 ||23
|-
|'''Se GW''' ||'''212''' ||'''6'''
|-
|Se sv GW ||469 ||24
|-
|'''Br GW''' ||'''216''' ||'''7'''
|-
|Br sv GW ||475 ||25
|-
|'''Kr GW''' ||'''252''' ||'''8'''
|-
|'''Rb sv GW''' ||'''221''' ||'''9'''
|-
|'''Sr sv GW''' ||'''225''' ||'''10'''
|-
|'''Y sv GW''' ||'''339''' ||'''11'''
|-
|'''Zr sv GW''' ||'''346''' ||'''12'''
|-
|'''Nb sv GW''' ||'''353''' ||'''13'''
|-
|'''Mo sv GW''' ||'''344''' ||'''14'''
|-
|'''Tc sv GW''' ||'''351''' ||'''15'''
|-
|'''Ru sv GW''' ||'''348''' ||'''16'''
|-
|'''Rh sv GW''' ||'''351''' ||'''17'''
|-
|Rh GW ||247 ||9
|-
|'''Pd sv GW''' ||'''356''' ||'''18'''
|-
|Pd GW ||251 ||10
|-
|'''Ag sv GW''' ||'''354''' ||'''19'''
|-
|Ag GW ||250 ||11
|-
|'''Cd sv GW''' ||'''361''' ||'''20'''
|-
|Cd GW ||254 ||12
|-
|'''In d GW''' ||'''279''' ||'''13'''
|-
|In sv GW ||366 ||21
|-
|'''Sn d GW''' ||'''260''' ||'''14'''
|-
|Sn sv GW ||368 ||22
|-
|'''Sb d GW''' ||'''263''' ||'''15'''
|-
|Sb sv GW ||372 ||23
|-
|Sb GW ||172 ||5
|-
|'''Te GW''' ||'''175''' ||'''6'''
|-
|Te sv GW ||376 ||24
|-
|'''I GW''' ||'''176''' ||'''7'''
|-
|I sv GW ||381 ||25
|-
|'''Xe GW''' ||'''180''' ||'''8'''
|-
|Xe sv GW ||400 ||26
|-
|'''Cs sv GW''' ||'''198''' ||'''9'''
|-
|'''Ba sv GW''' ||'''238''' ||'''10'''
|-
|'''La GW''' ||'''313''' ||'''11'''
|-
|'''Ce GW''' ||'''305''' ||'''12'''
|-
|'''Hf sv GW''' ||'''283''' ||'''12'''
|-
|'''Ta sv GW''' ||'''286''' ||'''13'''
|-
|'''W sv GW''' ||'''317''' ||'''14'''
|-
|'''Re sv GW''' ||'''317''' ||'''15'''
|-
|'''Os sv GW''' ||'''320''' ||'''16'''
|-
|'''Ir sv GW''' ||'''320''' ||'''17'''
|-
|'''Pt sv GW''' ||'''324''' ||'''18'''
|-
|Pt GW ||249 ||10
|-
|'''Au sv GW''' ||'''306''' ||'''19'''
|-
|Au GW ||248 ||11
|-
|'''Hg sv GW''' ||'''312''' ||'''20'''
|-
|'''Tl d GW''' ||'''237''' ||'''15'''
|-
|Tl sv GW ||316 ||21
|-
|'''Pb d GW''' ||'''238''' ||'''16'''
|-
|Pb sv GW ||317 ||22
|-
|'''Bi d GW''' ||'''261''' ||'''17'''
|-
|Bi GW ||147 ||5
|-
|Bi sv GW ||323 ||23
|-
|'''Po d GW''' ||'''267''' ||'''18'''
|-
|Po sv GW ||326 ||24
|-
|'''At d GW''' ||'''266''' ||'''17'''
|-
|At sv GW ||328 ||25
|-
|'''Rn d GW''' ||'''268''' ||'''18'''
|-
|Rn sv GW ||331 ||26
|-
|}
 
== Further recommendations for the potentials ==
 
In the following we further explanation the potentials for very important element groups.
 
=== 1st row elements ===
 
{| class="wikitable"
|-
|Element (and appendix) ||default cutoff ENMAX (eV)
|-
|'''B''' ||'''318''' ||'''3'''
|-
|B_h ||700 ||3
|-
|B_s ||250  ||3
|-
|'''C''' ||'''400'''    ||'''4'''
|-
|C_h ||700 ||4
|-
|C_s ||273  ||4
|-
|'''N''' ||'''400'''    ||'''5'''
|-
|N_h ||700              ||5
|-
|N_s ||250           ||5
|-
|'''O''' ||'''400'''  ||'''6'''
|-
|O_h ||700 ||6
|-
|O_s ||250  ||6
|-
|'''F''' ||'''400'''    ||'''7'''
|-
|F_h ||700   ||7
|-
|F_s ||250   ||7
|-
|Ne ||343    ||8
|-
|}
 
For the 1st row elements three PAW versions exist. For most purposes the standard versions should be used. They yield reliable results for cutoffs between 325 and 400 eV, where 370-400 eV are required to accurately predict vibrational properties, but binding geometries and energy differences are well reproduced at 325 eV. The typical bond length errors for first row dimers (N<sub>2</sub>, CO, O<sub>2</sub>) are about 1% (compared to more accurate DFT calculations, not experiment). The hard pseudopotentials _h give results that are essentially identical to the best DFT calculations presently available (FLAPW, or Gaussian with huge basis sets). The soft potentials are optimised to work around 250-280 eV. They yield very reliable description for most oxides, such as V<sub>x</sub>O<sub>y</sub>, TiO<sub>2</sub>, CeO<sub>2</sub>, but fail to describe some structural details in zeolites (i.e. cell parameters, and volume).
 
For HF and hybrid tpye calculations, we strictly recommend the use of the standard, standard GW, or of the hard potentials. For instance, the O_s potential can cause unacceptably large error even in transition metal oxides, even though the potential works reliable at the PBE level.
 
=== Alkali and alkali-earth elements (simple metals) ===
 
For Li (and Be), a standard potential and a potential that treats the 1s shell as valence states are available (Li_sv, Be_sv). For many applications one should use the _sv potential since their transferability is much improved compared to the standard potentials.
 
For the other alkali and alkali-earth elements the semi-core s and p states should be treated as valence states as well. For lighter elements (Na-Ca) it is usually sufficient to treat the the 2p and 3p states, respectively, as valence states (_pv), whereas for Rb-Sr the 4s, 4p and  5s, 5p states, respectively, must be treated as valence states (_sv). The standard potentials are listed below (default energy cutoffs are specified as well but might vary from one release to the other):
 
== References ==
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[[Category:PAW]][[Category:Howto]]

Latest revision as of 15:38, 11 June 2024